Present study has been conducted to see the relative effects of adding N: to fuel-side and air-side on flame structure, soot formation and NOx emissions. Experiments were carried out to ascertain to what degree chemical kinetics and/or molecular transport effects can explain the differences in soot formation and NOx emission by studying laminar diffusion flames. Direct photograph was taken to see the flame structure. CARS techniques was used to get the flame temperature profiles. And spatial distribution of soot could be obtained by PLII method. CHEMKIN code was also used to estimate the global residence time to predict NOx emissions at each condition. Results from these studies indicate that fuel-side dilution is more effective than air-side dilution in view of NOx emissions. However, air-side dilution shows greater effectiveness over fuel-side dilution in soot formation. And turbulent mixing and heat transfer problems were thought to be considered in practical applications.