In this paper, we studied the effect of asymmetrical 3rd order IMD of power amplifier due to changes in modulation frequency on IMD cancellation performance. The phase extraction method for determining asymmetric rate for phase distortion of IMD is proposed and the phase difference between lower and upper 3rd order IMD is measured by this method. The phase compensation circuit to decrease the phase difference is also designed and fabricated. From the measurement results using the phase compensation circuit applied to 5 W RF power amplifier fur PCS applications, the 3rd order IMD cancellation performance can be achieved up to 2-tone spacing 1.5 MHz (phase difference within 10$^{circ}$).