- 기계적 합금화법에 의해 제조된 Fe$_{0.98}$Mn$_{0.02}$Si$_2$의 상변태와 산화특성
- ㆍ 저자명
- 심웅식,이동복,어순철
- ㆍ 간행물명
- 한국표면공학회지
- ㆍ 권/호정보
- 2003년|36권 2호|pp.200-205 (6 pages)
- ㆍ 발행정보
- 한국표면공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Thermoelectric p-type $Fe_{0.98}$ $Mn_{ 0.02}$$Si_2$ bulk specimens have been produced by mechanical alloying and consolidation by vacuum hot pressing. The subsequent isothermal annealing was not able to fully transform the mestastable as -milled powders into the $eta$ $-FeSi_2$ phase, so that the obtained matrix consisted of not only thermoelectric semiconducting $eta$-FeSi$_2$ but also some residual, untransformed metallic $alpha$ $- Fe_2$$Si_{ 5}$ and $varepsilon$-FeSi mixtures. Interestingly, $eta$ - $FeSi_2$ was more easily obtained in the low density specimen when compared to the high density specimen. The oxidation at 700 and $800^{circ}C$ in air led to the phase transformation of the above described iron - silicides and the formation of a thin silica surface layer.