Cycle test for developed phase change material (PCM) is necessary in order to analyze the variation of latent heat, which decreases with time by deterioration. 7-history method and measurement using heat flux meter are appropriate for the cycle test in a tube filled with PCM because they do not need an extraction of sample in measuring the heat of fusion. In the present study, these methods were applied to a PCM having a melting point below a room temperature, different from the past studies for PCMs melting above a room temperature. As a result of experiment using pure water as specimen, we can obtain reason-able values for heat of fusion by both methods.