The present study investigates effects of flow velocity on the convective heat/mass transfer characteristics in wavy ducts of a primary surface heat exchanger application. Local heat/mass transfer coefficients on the wavy duct sidewall are determined by using a naphthalene sublimation technique. The flow visualization technique is used to understand the overall flow structures inside the duct. The aspect ratio and corrugation angle of the wavy duct is fixed at 7.3 and 145$^{circ}$ respectively, and the Reynolds numbers, based on the duct hydraulic diameter, vary from 100 to 5,000. The results show that there exist complex secondary flows and transfer processes resulting in non-uniform distributions of the heat/mass transfer coefficients on the duct side walls. At low Re (Re<1000), relatively high heat/mass transfer regions like cell shape appear on both pressure and suction side wall due to the secondary vortex flows called Taylor-Gortler vortices perpendicular to the main flow direction. However, at high Re (Re>1000), these secondary flow cells disappear and boundary layer type flow characteristics are observed on pressure side wall and high heat/mass transfer region by the flow reattachment appears on the suction side wall. The average heat/mass transfer coefficients are higher than those of the smooth circular duct due to the secondary flows inside wavy duct. And also friction factors are about two times greater than those of the smooth circular duct.