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Homologous 산화물 ZnkIn2O3+k(k=1∼9)의 열전 특성
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  • Homologous 산화물 ZnkIn2O3+k(k=1∼9)의 열전 특성
저자명
남윤선,최정규,홍정오,이영호,이명현,서원선,Nam. Yun-Sun,Choi. Joung-Kyu,Hong. Jeong-Oh,Lee. Young-Ho,Lee. Myung-Hyun,Seo. Won-Seon
간행물명
한국재료학회지
권/호정보
2003년|13권 8호|pp.543-549 (7 pages)
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한국재료학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

In order to investigate the thermoelectric properties of $Zn_{k}$ $In_2$$O_{ 3+k}$ homologous compounds, the samples of $Zn_{k}$ /$In_2$$O_{3+k}$ / (k = integer between 1 and 9) were prepared by calcining the mixed powders of ZnO and $In_2$$O_3$fellowed by sintering at 1823 K for 2 hours in air, and their electrical conductivities and Seebeck coefficients were measured as a function of temperature in the range of 500 K to 1150 K. X-ray diffraction analysis of the sintered samples clarified that single-phase specimens were obtained for $Zn_{k} /$In_2$$O_{3+k}$ with k = 3, 4, 5, 7, 8, 9. Electrical conductivity of the $Zn_{k}$ $In_2$$O_{3+k}$ / decreased with increasing temperature, and decreased with increasing k for k $geq$ 3. The Seebeck coefficient was negative at all the temperatures for all compositions, confirming that $Zn_{k}$ $In_2$$O_{3+k}$ / is an n-type semiconductor. Absolute values of the Seebeck coefficient increased linearly with increasing temperature and increased with increasing k for k $geq$ 3. The temperature dependence of the Seebeck coefficient indicated that Z $n_{k}$I $n_2$ $O_{3+k}$ could be treated as an extrinsic degenerate semiconductor. Figure-of-merits of Z $n_{k}$I $n_2$ $O_{3+k}$ were evaluated from the measured electrical conductivity and Seebeck coefficient, and the reported thermal conductivity. Z $n_{7}$ I $n_2$ $O_{10}$ has the largest figure-of-merit over all the temperatures, and its highest value was $1.5{ imes}$10$^{-4}$ $K^{-1}$ at 1145 K.5 K.