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$^{11}B$ Nuclear Magnetic Resonance Study of Calcium-hexaborides
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  • $^{11}B$ Nuclear Magnetic Resonance Study of Calcium-hexaborides
  • $^{11}B$ Nuclear Magnetic Resonance Study of Calcium-hexaborides
저자명
Mean. B.J.,Lee. K.H.,Kang. K.H.,Lee. Moo-Hee,Lee. J.S.,Cho. B.K.
간행물명
Journal of the Korean magnetic resonance society
권/호정보
2003년|7권 2호|pp.80-88 (9 pages)
발행정보
한국자기공명학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

We have performed $^{11}$ B nuclear magnetic resonance (NMR) measurements to microscopically investigate an electronic structure of the ferromagnetic state in three different compositions of calcium-hexaboride single crystals. Although the crystal structure of Ca $B_{6}$ is cubic and three NMR lines may be expected for the nuclear spin 3/2 of $_{11}$ B, a larger number of NMR resonance peaks have been observed. The frequency and intensity of those peaks distinctively changes depending on the angle between crystalline axis and magnetic field. Analyzing this behavior, we find that the electric field gradient(EFG) tensor at the boron has its principal axis perpendicular to the six cubic faces with a quadrupole resonance frequency $v_{Q}$ 600 kHz. Even though the magnetization data highlight the ferromagnetic hysteresis, $^{11}$ B NMR linewidth data show no clear microscopic evidence of the ferromagnetic state in three different compositions of Ca $B_{6}$ single crystals.s.