The effect of nose radius on aerodynamic heating is investigated by using the Navier-Stokes code extended to thermochemical nonequilibrium airflow, Spherical blunt bodies, whose nose radius varies from 0.O03048 m to 0.6096 m, flying at Mach 25 at an altitude of 53.34 km are considered. Comparison of heat flux at stagnation point with the solution of Viscous Shock Layer and Fay-Riddell are made. Results show that the flow for very small radius is in a nearly frozen state, and therefore the heat flux due to diffusion is smaller than that due to translational energy. As the radius becomes larger, the portion of heat flux by diffusion becomes greater than that of heat flux by translational temperature and approaches to a constant value.