A level set method is combined with the volume-of-fluid method so that the coupled method can not only calculate an interfacial curvature accurately but also can achieve mass conservation well. The coupled level set and volume-of-fluid(CLSVOF) method is efficiently implemented by employing an interface reconstruction algorithm which is based on the explicit relationship between the interface configuration and the fluid volume function. The CLSVOF method is applied for numerical simulation of droplet impact on solid surfaces with variable contact angles. The numerical results are found to preserve mass conservation and to be in good agreement with the data reported in the literature. Also, the present method proved to be applicable to the complex phenomena such as breakup and rebound of a droplet.