Calcium sulfoalumiante(CSA) was prepared for using natural calcite($CaCO_3$) and industrial by-products and wastes, such as $Al(OH)_3,;CaSO_4{cdot}2H_2O$. The mixture of raw materials was fired at 20, 400, 600, $1200^{circ}C$ for 1h and cooled rapidly in air. The cement replaced by $10 wt {\%} C_4A_3S$ expansive additives was investigated by the measurement of the hydration products and compressive strength, setting time, expansion at wet curing condition. $C_4A_3S$ was found in x-ray diffraction pattern over the temperature $1200^{circ}C$. The setting time or the cement pastes added clinkers fired at different temperature was shorter than ordinary portland cement. The compressive strength was higher than the ordinary portland cement about $20{~}30\%$. The mainly hydration products were ettringite, and $Ca(OH)_2$. The expansion due to the formation of ettringite during hydration decreased the drying shrinkage of hardened cement rather than the ordinary portland cement.