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Hg2+-Selective Chemosensor Derived from 8-Hydroxyquinoline Having Benzothiazole Function in Aqueous Environment
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  • Hg2+-Selective Chemosensor Derived from 8-Hydroxyquinoline Having Benzothiazole Function in Aqueous Environment
  • Hg2+-Selective Chemosensor Derived from 8-Hydroxyquinoline Having Benzothiazole Function in Aqueous Environment
저자명
Youk. Jin-Soo,Kim. Young-Hee,Kim. Eun-Jin,Youn. Na-Jin,Chang. Suk-Kyu
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2004년|25권 6호|pp.869-872 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Newly synthesized 8-hydroxyquinoline based benzothiazole derivative 2 showed a distinctive $Hg^{2+}$-selectivity over other transition metal ions in aqueous solution. The fluorescence emission at 455 nm of 2 was completely quenched upon interaction with $Hg^{2+}$ ions in dioxane-$H_2O$ system (9 : 1, v/v). The selectivity was decreased in the order of $Hg^{2+};>>;Cu^{2+};>;Cd^{2+};>;Pb^{2+};{ hickapprox};Zn^{2+};{ hickapprox};Ni^{2+},;and;Hg^{2+}$ concentration dependent fluorescence quenching profile was observed in the presence of common interfering metal ions as background. The fluorescence behavior of 2 suggests that the prepared compound could be used as a fluorescent signaling subunit for the construction of new $Hg^{2+}$-sensitive ON-OFF type supramolecular switching systems.