The general method which changes sub-cooling of refrigerant is to control the expansion valve in the state of mixing with liquid and gas phase. In this study, the performance of vehicle air conditioning system is to control either changing the expansion valve or adding the sub condenser. Therefore, this research finally is tested in case of the fourth test procedure, the second test was suitable for a valve opening area due to adjusting valve slope in comparison with the other test. The other test except for the second test happened to do liquid back due to the excessively liquified refrigerant into the system. In conclusion, the second test was appeared not to be influenced upon liquid back, and it is to expect positive performance by controlling an expansion valve. Therefore, it will be also useful to research for an increase of compressor efficiency Performance improvement of an air conditioner is to reinforce the suction performance of the evaporator and increase the sub-cooling, which make use of the sub-cooling system.