In the present study, the improvement of absorption characteristics on combined heat and mass transfer process in a falling film of a vertical absorber by change of geometric parameters were studied experimentally and analytically. The energy and diffusion equations are solved simultaneously to give the temperature and concentration variations at the liquid solution-refrigerant vapor interface and at the wall. Absorption behaviors of heat and mass transfer were analyzed through falling film of the LiBr aqueous solution contacted by refrigerant vapor in the absorber. Effects of film Reynolds number, geometric parameters by insert device (spring) and flow pattern on heat and mass transfer performances have been also investigated. Especially, effects of the flow pattern by geometric parameters have been considered to observe the total heat and mass transfer rates through falling film along the absorber. As a numerical and experimental result, maximum absorption rate was shown at the wave-flow by insert device (spring). The error ranges between experiment and analysis were from 5.8 to 12％ at Re$_{f}$ > 100.0.