As air pollution has become an important issue across the world, studies of clean fuel are on going to reduce combustion emissions. One example is development of the LPLi(Liquefied Phase LPG injection) engine. Some problems are occurred during development. One of the problems is icing phenomenon at injector tip due to evaporation potential heat when liquid LPG is injected. If the Icing is raised at injector tip or injector inserting hole, it disturbs fuel injection. And if the ice particles are inducted into cylinder, it brings problems associated with control of emission and air/fuel ratio. In order to solve the problems, a rig system was set up and observed Icing of injector tip. Engine test was carried out for visualization of injector tip icing and its effects on combustion and emissions.