DS-COMA is now a matured multiple access technology that utilizes spreading codes for user separation. In this paper, we attempt to improve the performance of a multiuser DS-COMA system with a unique chip shaping code called Carrier Interferometry (CI) code. The CI codes exhibit an excellent correlation property that can be used in many applications. In DS-COMA with CI codes (CI/DS-COMA), the symbols are spread by a spreading code and then the chip signals are shaped using a CI code. Due to the correlation property of the CI code, a diversity gain from the shaped chip signals is achieved and the performance of DS-COMA is significantly improved. Comparison study demonstrates that the DS-COMA with CI outperforms the conventional DS-COMA system in multiuser environments.