The allowable exhaust standard has been intensified as a part of the countermeasure to decrease air pollution in the world. As the cars with an alternative fuel starts to get into the spotlight, the cars with low emission has been introduced and exhaust gas regulation forced in this country. These days, LPG vehicles, which infrastructure of fuel was already built up, and CNG vehicles are recognized for alternative fuel cars in this country. In this study, the constant volume combustion chamber was manufactured and used for experiments to obtain the ignition characteristics of LPG fuel and the optimal ignition energy. The experiment measured the combustion characteristics, in regard to the change of combustion variable, and the change of ignition energy. During the combustion of fuel, the maximum temperature inside the combustion chamber is higher when the initial pressure is higher. The burning velocity also seems to have the same characteristic as the temperature. However, the heat flux did not change much with the theoretical correct mixture but the various initial temperature of the combustion chamber. The heat flux got faster and ignition energy bigger as the dwell time of the ignition system expanded. When the dwell time get longer, the ignition energy also increased then fixed. The ignition energy increased as the initial pressure inside the combustion chamber higher. The heat flux got faster as the dwell time expanded.