- Ba(Mg1/3Nb2/3)O3 - La(Mg2/3Nb1/3)O3복합 페로브스카이트 화합물의 결정구조
- ㆍ 저자명
- 백종후,이미재,최병현,지미정,임은경,남산
- ㆍ 간행물명
- 전기전자재료학회논문지
- ㆍ 권/호정보
- 2004년|17권 7호|pp.718-723 (6 pages)
- ㆍ 발행정보
- 한국전기전자재료학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Crystal structure of $(Ba-{1-x}La_x)[Mg_frac{1+x}{3}}Nb_frac{{2-x}{3}}]O_3$ (BLMN) ceramics with 0leq1x geq was investigated using synchrotron X-ray powder diffraction (XRD) and high reso(B $a_{l-x}$L $a_{x}$)[M $g_{(1+x)}$3/N $b_{(2-x)/3}$] $O_3$lution transmission electron microscopy (HRTEM). When the La content, x, is above 0.1, the 1:2 ordered hexagonal structure found in Ba($Mg_frac{1}{3}Nb_frac{2}{3}})O_3$(BMN) was transformed into 1:1 ordered cubic structure. The 1:1 ordered cubic structure was maintained up to x=0.7. When x exceeded 0.7, however, BLMN was transformed into 1:1 ordered structure which has cation displacement and in-phase and anti-phase tilt of octahedra.dra.