This paper reviews dynamic programming (DP), surveys approximate solution methods for it, and considers their applicability to process control problems. Reinforcement Learning (RL) and Neuro-Dynamic Programming (NDP), which can be viewed as approximate DP techniques, are already established techniques for solving difficult multi-stage decision problems in the fields of operations research, computer science, and robotics. Owing to the significant disparity of problem formulations and objective, however, the algorithms and techniques available from these fields are not directly applicable to process control problems, and reformulations based on accurate understanding of these techniques are needed. We categorize the currently available approximate solution techniques fur dynamic programming and identify those most suitable for process control problems. Several open issues are also identified and discussed.