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Cocrystallization of Poly(1,4-cyclohexylenedimethylene terephthalate-co-hexamethylene terephthalate) Copolymers
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  • Cocrystallization of Poly(1,4-cyclohexylenedimethylene terephthalate-co-hexamethylene terephthalate) Copolymers
  • Cocrystallization of Poly(1,4-cyclohexylenedimethylene terephthalate-co-hexamethylene terephthalate) Copolymers
저자명
Jeong. Young-Gyu,Jo. Won-Ho,Lee. Sang-Cheol
간행물명
Macromolecular research
권/호정보
2004년|12권 5호|pp.459-465 (7 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

We have synthesized poly(l,4-cyclohexylenedimethylene terephthalate-co-hexamethylene terephthalate) [P(CT-co-HT)] random copolymers having various comonomer contents, from 0 to 100 mol% HT, by melt-condensation and have investigated their crystallization behavior by using differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD). We observed that P(CT-co-HT)s exhibit clear melting and crystallization peaks in their DSC thermograms and sharp diffraction peaks in their WAXD patterns for all of their copolymer compositions as a result of cocrystallization of the CT and HT units, even though the copolymers are statistically random copolymers. When we plotted the melting and crystallization temperatures of P(CT-co-HT)s and the d-spacings of all the reflections against the copolymer composition, we observed a eutectic point at ca. 80 mol% HT, which suggests that a crystal transition occured from a PCT-type crystal to a PHT-type crystal. Both the DSC and WAXD results support the notion that P(CT-co-HT) copolymers undergo an isodimorphic cocrystallization.