This study analyzes the interrelationship with air pollution quality and land used patterns, and analyzes the history and optimal allocation of TMS using GIS. Seasonal air pollution map are maded of TMS data in study area, and land used patterns based on Land Cover Classification Map are reclassified as residential area, commercial area, industrial area, traffic concentrated area, and non-Polluted area. Pollution sources can be identified through analyzing the correlation of air pollution and land used patterns by GIS spatial overlaying technique. Hence, the result shows that it coincides with the characteristics of conventional air pollution. Air pollution quality measured by TMS shows similar to that of its near stations or the same land used patterns, through the history and allocation analysis of TMS. Therefore, it is need to consider these characteristics in setting TMS positions in the future.