- 규석광으로부터 직접 질화법에 의한 질화규소의 합성
- ㆍ 저자명
- 손용운,주성민,정헌생,Sohn. Yong-Un,Joo. Sung-Min,Chung. Hun-Saeng
- ㆍ 간행물명
- 한국재료학회지
- ㆍ 권/호정보
- 2004년|14권 5호|pp.358-362 (5 pages)
- ㆍ 발행정보
- 한국재료학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
$Si_3$$N_4$ ceramics have been identified as one of the promising structural ceramics. This study has been carried out to investigate of the synthetic behaviors of $Si_3$$N_4$ derived from domestic silica-stone by direct nitriding method. The silicon nitridation reaction has been studied in the temperature range of $1300~1550^{circ}C$. Below the $1400^{circ}C$, the nitriding rate was measured to be 16%. For the temperatures higher than the $1400^{circ}C$, $eta$-$Si_3$$N_4$ phase was formed mainly, and the nitriding rate showed above 98%. With the increasing of sample weight of silicon powder, the nitriding rate and $eta$-$Si_3$$N_4$ phase increased at $1400^{circ}C$ for 2 hours. The shape and particle size of$ Si_3$$N_4$ powder synthesized at $1400^{circ}C$ for 2 hours showed the irregular angular-type and 10 $mu extrm{m}$, respectively.