- 기계적 합금화 p-type FeSi2의 플라즈마 용사 성형 및 열전 특성
- ㆍ 저자명
- 최문관,어순철,김일호,Choi. Mun-Gwan,Ur. Soon-Chul,Kim. IL-Ho
- ㆍ 간행물명
- 한국재료학회지
- ㆍ 권/호정보
- 2004년|14권 3호|pp.218-223 (6 pages)
- ㆍ 발행정보
- 한국재료학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
P-type $eta$-FeSi$_2$ with a nominal composition of $Fe_{0.92}Mn_{0.08}Si_2$ powders has been produced by mechanical alloying process. As-milled powders were spray dried and consolidated by atmospheric plasma thermal spraying as a rapid sintering process. As-milled powders were of metastable state and fully transformed to $eta$-$FeSi_2$ phase by subsequent isothermal annealing. However, as-thermal sprayed $Fe_{0.92}Mn_{0.08}Si_2$ consisted of untransformed mixture of $alpha$-$Fe_2Si_{5}$ and $varepsilon$-FeSi phases. Isothermal annealing has been carried out to induce transformation to the thermoelectric semiconducting $eta$-$FeSi_2$ phase. Isothermal annealing at $845^{circ}C$ in vacuum gradually led to the thermoelectric semiconducting $eta$-$FeSi_2$ phase transformation, but some residual metallic $alpha$ and $varepsilon$ phases were unavoidable even after prolonged annealing. Thermoelectric properties of $eta$-$FeSi_2$ materials before and after isothermal annealing were evaluated. Seebeck coefficient increased and electric conductivity decreased with increasing annealing time due to the phase transition from metallic phases to semiconducting phases. Thermoelectric properties showed gradual increment, but overall properties appeared to be inferior to those of vacuum hot pressed specimens.