With increasing interests in environment matters over the world, incessant efforts to develop products which meet these environmental requirements have been made also in paint industry. Among the efforts in this field, UV(Ultra Violet) curing system is focused as one of most potential system. It is because this system not only proved to be environmentally friendly compared with heat curing system or other system but also has economical merit of smaller facility, less energy consumption, and better productivity. Superior properties in many application is surely one of its dominant merit. With these advantage UV system is applied to a variety of industrial fields and expected to have continuous growth in the future. As practical application of UV system has shown lasting progress, R&D on basic material of this system keeps up with. This is a study on photo-initiator that is a fundamental substance in UV curing method and amine, its aid for better effect. After reviewing on them in the aspects of function, economy, and stability, optimal foumula is pursued through experiments when applied to real products.