This study investigates the transition of flows in a natural convection problem with periodic wall temperatures of the form, T_L=T₁＋δ Tsinκχ and T_L=T₂＋δ Tsinκχ .The fluid considered is air with P_γ=0.7. In the conduction-dominated regime with a small Rayleigh number, two large cells are formed over one wave length, for all wave numbers. When k≤1.8, the flow becomes unstable with increase of the Rayleigh number, and multicellular convection occurs above a critical Rayleigh number. The flow patterns are classified by the number of eddies over one wave length, and several kinds of transition phenomena, such as 2→3→4, 4→3→2, and 2→4 eddy flow, occur with increase( or decrease) of the Rayleigh number. Dual solutions are found above a critical Rayleigh number, and an anomalous bifurcation is observed.