This paper analyzed the characteristics of daily ozone variations over Kangreung and Wonju. It was found that the diurnal cycle of ozone over Wonju has a primary ozone peak in the afternoon and a minimum around sunrise, which is a typical diurnal ozone cycle observable in the urban area. However, the cycle over Kangreung shows a primary peak in the afternoon and secondary peak around 3 a.m. The amounts of ozone in the secondary peak is occasionally higher than that in the primary peak. This nocturnal ozone peak is frequently observed year-round, and the highest frequency and extent are observed in spring. The possible cause of this nocturnal ozone increase was investigated using meteorological parameters and the HYSPLIT trajectory model. It was found that the nocturnal ozone peak is highly correlated with strong wind speed, which has led to positive temperature anomaly. The trajectory model revealed that when the secondary peak occurred, the air was originated from the west and a sinking motion subsequently followed. These findings suggested that when the westerly wind is strongest in spring, the polluted airs from urban areas are transported to the upper boundary layer over Kangreung area. In the case of strong wind during the night, nocturnal ozone peaks were produced by active vertical mixing between lower boundary and upper boundary layers.