In this paper, thermodynamic design data for heating of double-effect absorption system using LiCl-water for evaporator heating source of sofar energy are investigated for the water-LiCl pair and a comparative study of the water-LiCl pair with the water-LiBr pair is given used for the computer simulation. The computer simulation is based on mass, material and heat balance equations for each part of the system. Coefficients of performance and flow ratios for effects of different operating temperatures are investigated. It is found that the heating COP is higher for the water -LiCl pair than for the water-LiBr pair, and FR is lower for the water-LiCl pair than for the water LiBr pair.