- Zr-Al-Cu-Ni계 합금의 비정질형성능에 미치는 Pd과 Ag 복합첨가의 영향
- ㆍ 저자명
- 김미혜,이병우,김성규,배차헌,정해용,Kim. Mi-Hye,Lee. Byung-Woo,Kim. Sung-Gyu,Bae. Cha-Hurn,Jeong. Hae-Yong
- ㆍ 간행물명
- 한국주조공학회지
- ㆍ 권/호정보
- 2004년|24권 1호|pp.40-44 (5 pages)
- ㆍ 발행정보
- 한국주조공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The influence of Pd and Ag additions on the thermal stability, the glass forming ability (GFA) and mechanical property of $Zr_{55}Al_{10}Cu_{20}Ni_{10}Pb_{(5-x)}Ag_x$ (x = $0{sim}5at%$) alloys obtained by melt spun and injection casting method have been investigated by using of X-ray diffraction, thermal analysis (DTA, DSC) and micro-Vickers hardness(Hv) testing. The thermal properties of melt-spun $Zr_{55}Al_{10}Cu_{20}Ni_{10}Pb_{(5-x)}Ag_x$ (x = $0{sim}5at%$) alloys exhibit a supercooled liquid region(${Delta}T_x$) exceeding 91 K before crystallization. The largest ${Delta}T_x$ reaches as large as 126 K for the $Zr_{55}Al_{10}Cu_{20}Ni_{10}Pb_5$ alloy. The reduced glass transition temperature, $T_{rg}$ increased with increasing Ag content. The largest $T_{rg}$ is obtained for the $Zr_{55}Al_{10}Cu_{10}Ni_{10}Ag_5$ alloy. The $Zr_{55}Al_{10}Cu_{10}Ni_{10}Ag_5$ bulk amorphous alloy rod with 3 mm in diameter was fabricated by injection casting. Hv increased with increasing Ag content and the largest value was obtained for the $Zr_{55}Al_{10}Cu_{10}Ni_{10}Ag_5$ bulk amorphous alloy.