In automotive industry, light weight vehicle is one of issues because of the air pollution and the protection of environment. Therefore, automotive manufacturers have tried to apply light materials such as aluminum to car body. Aluminum welding using laser has some advantages high energy density and high productivity. It is very important to understand behavior of plasma and keyhole in order to improve weld quality and monitor the weld state. In this study, spectral analysis was carried out to verify the spectrum for plasma which is generated in laser welding of A 6000 aluminum alloy. Two photodiodes which cover the range of plasma wavelength was used to measure light emission during laser welding according to assist gas flow rate and welding speed. Analysis of relationship between sensor signals of welding variables and formation of keyhole and plasma is performed. To determine the level of significance, analysis of variation (ANOVA) was carried out.