- 염화동 수용액으로부터 Cu 미립자의 합성
- ㆍ 저자명
- 윤지희,권현우,유연태,김병규,김광수,Yoon. Ji-hee,Kwon. Hyun-Woo,Yu. Yeon-tae,Kim. Byoung-Gyu,Kim. Gwang-soo
- ㆍ 간행물명
- 한국재료학회지
- ㆍ 권/호정보
- 2005년|15권 4호|pp.263-270 (8 pages)
- ㆍ 발행정보
- 한국재료학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
In order to prepare the uniform copper particles from copper chloride solution, the reduction behavior of copper particles from copper chloride and the effects of reduction agent and dispersing agent was investigated. In the case that 2.56 M of $C_6H_8O_6$ was used as a reduction agent, the highly dispersed Cu particles with sharp size distribution were generated from 0.96M of copper chloride solution, and the size of Cu particles was $6~10;{mu}m$. To form $Cu(NH_3)_4Cl_2$ complex solution, $NH_4OH$ was added in the copper chloride solution before the reductive reaction of Cu ion. The generated Cu particles have a two kind of shape, spherical and rod-like. In the case that $N_2H_4{cdot}H_2O$ was used as a reduction agent, the very fine spherical Cu particles with the size of $0.2~0.5;{mu}m$ was obtained. Arabic gum as a dispersing agent was more effective than $Na_4P_2O_7{cdot}10H_2O$.