- 액상환원법에 의한 CuO-H2O 슬러리로부터 미세 구리분말의 제조
- ㆍ 저자명
- 안종관,김동진,이익규,이재령,양환진,Ahn. Jong-Gwan,Kim. Dong-Jin,Lee. Ik-Kyu,Lee. Jaeryeung,Huanzhen. Liang
- ㆍ 간행물명
- 한국분말야금학회지
- ㆍ 권/호정보
- 2005년|12권 3호|pp.192-200 (9 pages)
- ㆍ 발행정보
- 한국분말야금학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Ultrafine copper powder was prepared from $CuO-H_2O$ slurry with hydrazine, a reductant, under $70^{circ}C$. The influence of various reaction parameters such as temperature, reaction time, molar ratio of $N_2H_4$, PvP and NaOH to Cu in aqueous solution had been studied on the morphology and powder phase of Cu powders obtained. The production ratio of Cu from CuO was increased with the ratio of $N_2H_4/Cu$ and the temperature. When the ratio of $N_2H_4/Cu$ was higher than 2.5 and the temperature was higher than $60^{circ}C$, CuO was completely reduced into Cu within 40 min. The crystalline size of Cu obtained became fine as the temperature increase, whereas the aggregation degree of particles was increased with the reaction time. The morphology of Cu powder depended on that of the precursor of CuO and processing conditions. The average particle size was about $0.5;{mu}m$.