In this paper, an investigation on high-Schmidt number (Sc=1670) mass transfer in turbulent flow around a rotating circular cylinder is carried out by Direct Numerical Simulation. The concentration field is computed for three different values of low Reynolds number, namely 161, 348 and 623 based on the cylinder radius and friction velocity. Statistical study reveals that the thickness of Nernst diffusive layer is very small compared with that of viscous sub-layer in the case of high Sc mass transfer. Strong correlation of concentration field with streamwise and vertical velocity components is observed. However, that is not the case with the spanwise velocity component. Instantaneous concentration visualization reveals that the length scale of concentration fluctuation typically decreases as Reynolds number increases. Statistical correlation between Sherwood number and Reynolds number is consistent with other experiments currently available.