Self-Assembly of Vanadium Borophosphate Cluster Anions: Synthesis and Structures of (NH4)(C2H10N2)5.5[Cu(C2H8N2)2]3[V2P2BO<S

Self-Assembly of Vanadium Borophosphate Cluster Anions: Synthesis and Structures of (NH₄)(C₂H₁₀N₂)_5.5[Cu(C₂H₈N₂)₂]₃[V₂P₂BO
Self-Assembly of Vanadium Borophosphate Cluster Anions: Synthesis and Structures of (NH₄)(C₂H₁₀N₂)_5.5[Cu(C₂H₈N₂)₂]₃[V₂P₂BO

ㆍ 저자명: Jung. Kyung-Na,Cho. Yoon-Suk,Yun. Ho-Seop,Do. Jung-Hwan
ㆍ 간행물명: Bulletin of the Korean Chemical Society
ㆍ 권/호정보: 2005년|26권 8호|pp.1185-1189 (5 pages)
ㆍ 발행정보: 대한화학회
ㆍ 파일정보: 정기간행물|ENG|
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ㆍ 주제분야: 기타

이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.

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기타언어초록

Two new copper vanadium borophosphate compounds, $(NH_4)(C_2H_{10}N_2)_{5.5}[Cu(C_2H_8N_2)_2]_3[V_2P_2BO_{12}]_6{cdot}17H_2O,;Cu-VBPO1;and;(NH_4)(C_2H_{10}N_2)_{3.5}[Cu(C_2H_8N_2)_2]_5[V_2P_2BO_{12}]_6{cdot}18H_2O$, Cu-VBPO2 have been hydrothermally synthesized and characterized by single crystal X-ray diffraction, thermogravimetric analysis, IR spectroscopy, and elemental analysis. The structure of Cu-VBPO1 contains a layer anion, {$[Cu(C_2H_8N_2)_2]_3[V_2P_2BO_{12}]_6$}$^{12-}$, whereas Cu-VBPO2 has an open framework anion, {$[Cu(C_2H_8N_2)_2]_5[V_2P_2BO_{12}]_6$}$^{8-}$. Crystal Data: $(NH_4)(C_2H_{10}N_2)_{5.5}[Cu(C_2H_8N_2)_2]_3[V_2P_2BO_{12}]_6{cdot}17H_2O$, monoclinic, space group I2/m (no. 12), $alpha$ = 15.809(1) $AA$, b = 31.107(2) $AA$, c = 12.9343(8) $AA$, $eta$ = 104.325(1)$^{circ}$, Z = 2; $(NH_4)(C_2H_{10}N_2)_{3.5}[Cu(C_2H_8N_2)_2]_5[V_2P_2BO_{12}]_6{cdot}18H_2O$, tetragonal, space group $P4_2$/mnm (no.136), $alpha$ = 26.832(1) $AA$, c = 18.021(1) $AA$, Z = 4.

키워드

Self-assembly Borophosphate Cluster Hydrothermal reaction

다운URL