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The Compatibilizing Effect of Maleic Anhydride in Ethylene-Vinyl Acetate (EVA)/Ethylene-${alpha}$-Olefin Copolymers Blends
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  • The Compatibilizing Effect of Maleic Anhydride in Ethylene-Vinyl Acetate (EVA)/Ethylene-${alpha}$-Olefin Copolymers Blends
  • The Compatibilizing Effect of Maleic Anhydride in Ethylene-Vinyl Acetate (EVA)/Ethylene-${alpha}$-Olefin Copolymers Blends
저자명
Park. Soo-Chul,Choe. Soon-Ja
간행물명
Macromolecular research
권/호정보
2005년|13권 4호|pp.297-305 (9 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The compatibilizing effect of maleic anhydride (MA) in the immiscible blends of EVA22 (vinyl acetate content 22%)/ethylene-${alpha}$-olefin copolymers with 1-butene (EtBC) and 1-octene (EtOC)) comonomers was studied. By adding 1, 2, and 3 phr of MA in the presence of dicumylperoxide, the morphology, tensile strength at break, and 100 and 300 % modulus of EVA22/EtBC and EVA22/EtOC blends were significantly enhanced. The melting point and crystallization point depression were observed upon the addition of MA. The changes in the ${eta}$ transition and glass transition temperature of ethylene-${alpha}$-olefin copolymers and ethylene-vinyl acetate copolymers, respectively, indicate that MA plays a role of compatibilizer for these immiscible blends. The TGA thermograms, measured from the blends with MA, show that thermal stability is slightly enhanced with MA, indicating that MA acts as a reinforcing agent either by grafting or crosslinking with other copolymers.