- 염기성 용액에서 마젠타 아조메틴 색소의 퇴색 반응속도와 메커니즘
- ㆍ 저자명
- 이중호,김정성,김창수,Lee. Joong-Ho,Kim. Jung-Sung,Kim. Chang-Su
- ㆍ 간행물명
- 한국환경과학회지
- ㆍ 권/호정보
- 2005년|14권 7호|pp.711-717 (7 pages)
- ㆍ 발행정보
- 한국환경과학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
A magenta azomethine dye(D) was synthesized from the reaction of 3-methyl-1-phenyl-2-pyrazoline-5-one with N,N-diethyl-1,4-phenylenediamine. The magenta azomethine dye was identified on the basis of elemental analysis, $^{13}C-NMR$, infrared, and GC/MS studies. The magenta azomethine dye was decomposed in a basic solution. Rate constants of the fading reaction of magenta azomethine dye in ethanol-water solvent were measured spectrophotometrically at 540 nm. Reaction rate was increased with the increase of $[OH^{-}];and;[H\_{2}O]$ in the region of $[H_{2}O]=11~40;M$. The reaction was governed by the following rate law. -d[D]/dt = ${k_o;+;k_{OH}[OH^-][H_{2O}]}[D]$ A possible mechanism consistent with the empirical rate law has been proposed.