The waterproofing in slab and wall of underground structure, have a couple of construction methods which are inside waterproofing methods for inner surface, and outside waterproofing methods for out wall and slab surface waterproofing. In resent years, however, it has been adapted the inside waterproofing construction method, as increasing of construction expenses cost and low workability and technology, nevertheless, outside waterproofing has set a most high value construction method. In inside waterproofing construction method, it is difficult to repair and assure durability and safety for concrete which has direct water-press. So, It is necessary for adopt the outside waterproofing method. For that reasons, this study based on the application for outside waterproofing method on the under ground structure, to more increase durability, to introduce mono adhesive sheet waterproofing materials. as considering chemical, physical properties.