- 분무건조법에 의해 제조된 Ti-Co-O계 산화물 분말의 환원/침탄반응에 미치는 코발트 산화물의 영향
- ㆍ 저자명
- 이길근,김찬영,Lee. Gil-Geun,Kim. Chan-Young
- ㆍ 간행물명
- 한국분말야금학회지
- ㆍ 권/호정보
- 2005년|12권 5호|pp.336-344 (9 pages)
- ㆍ 발행정보
- 한국분말야금학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
In the present study, the focus is on the effect of cobalt oxide powder in the carbothermal reduction of the titanium-cobalt-oxygen based oxide powder by solid carbon for the optimizing synthesis process of ultra fine TiC/Co composite powder. The titanium-cobalt-oxygen based oxide powder was prepared by the combination of the spray drying and desalting processes using the titanium dioxide powder and cobalt nitrate as the raw materials. The titanium-cobalt-oxygen based oxide powder was mixed with carbon black, and then this mixture was carbothermally reduced under flowing argon atmosphere. Changes in the phase structure and thermal gravity of the mixture during carbothermal reduction were analysed using XRD and TGA. Titanium-cobalt-oxygen based oxide powder desalted at $600^{circ}C$ had a mixture of $TiO_2;and;Co_{3}O_4$. And the one desalted at $800^{circ}C$ had a mixture of $TiO_2;and;CoTiO_3$. In the case of the former powder, the reduction of cobalt oxide powder in the titanium-cobalt-oxygen based oxide powder occurred at lower temperature than the latter one. However, the carbothermal reduction of titanium dioxide powder in the titanium-cobalt-oxygen based oxide powder with a mixture of $TiO_2;and;Co_{3}O_4$ occurred at higher temperature than the one with a mixture of $TiO_2;and;CoTiO_3$. And also, the former powder showed a lower TiC formation ability than the latter one.