O-ring seal is an essential component in various mechanical apparatuses for a sealing of oil container and pressure vessels. This paper presents the sealing pressure and compressive contact behaviors of hi-polymer O-rings, which is made by an outer shell of FFKM material and an inner solid ring of FKM one. The contact normal pressure and its ratios are measured by experimental method with an automatic control system of the working temperature and analyzed numerically by using the non-linear Marc FEM program. The results show reasonably good agreements between the computed FEM results and measured ones when the operating temperature is kom normal temperature of $18^{circ}C$ and a high temperature of $300^{circ}C$ But the compared values between the computed and tested results show a little difference because of the increased temperature, which is related to the non-linear parameter of the O-ring material. Bi-polymer 0-ring shows a good contact normal stress and compression behavior for a given operation temperature and compression ratio.