Synthesis of silver nanoparticles by the supersonic nozzle expansion method with corona discharge ions was investigated. Corona discharge ions functioned as seeds for heterogeneous nucleation in the silver nanoparticles formation process and provided silver nanoparticles with electronic repulsive force that prevents aggregation of the particles. For ion ejecting, we used sonic-jet corona discharger. Upon application of the corona discharge ions, the mean diameter of the produced particles was decreased from 12.54 to 6.22nm and the standard deviation was decreased from 5.02 to 3.34nm. In addition, the agglomeration of silver nanoparticles was reduced.