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The Utilization of Waste Seashells for $H_{2}S$ Removal
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  • The Utilization of Waste Seashells for $H_{2}S$ Removal
  • The Utilization of Waste Seashells for $H_{2}S$ Removal
저자명
Kim. Young-Sik,Suh. Jeong-Min,Jang. Sung-Ho
간행물명
韓國環境保健學會誌
권/호정보
2005년|31권 6호|pp.483-488 (6 pages)
발행정보
한국환경보건학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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The waste seashells were used for the removal of hydrogen sulfide from a hot gas stream. The sulphidation of waste seashells with $H_{2}$S was studied in a thermogravimetric analyzer at temperature between 600 and $800^{circ}C$. The desulfurization performance of the waste seashell sorbents was experimentally tested in a fixed bed reactor system. Sulfidation experiments performed under reaction conditions similar to those at the exit of a coal gasifier showed that preparation procedure and technique, the type and the amount of seashell, and the size of the seashell affect the $H_{2}$S removal capacity of the sorbents. The pore structure of fresh and sulfided seashell sorbents was analyzed using mercury porosimetry, nitrogen adsorption, and scanning electron microscopy (SEM). Measurements of the reaction of $H_{2}$S with waste seashells show that particles smaller than 0.631 mm can achieve high conversion to CaS. According to TGA and fixed bed reactor results, temperature had influenced on $H_{2}$S removal efficiency. As desulfurization temperature increased, desulfurization efficiency increased. Also, maximum desulfurization efficiency was observed at $800^{circ}C$. Desulfurization was related to calcinations temperature.