- ABC-EAREX2005 기간 동안 제주도 고산지역 대기 중 가스상 및 입자상 물질의 분포특성
- ㆍ 저자명
- 문광주,한진석,공부주,이민도,정일록,Moon. K.J.,Han. J.S.,Kong. B.J.,Lee. M.D.,Jung. I.R.
- ㆍ 간행물명
- 한국대기환경학회지
- ㆍ 권/호정보
- 2005년|21권 6호|pp.675-687 (13 pages)
- ㆍ 발행정보
- 한국대기환경학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
In this study, the cyclone/denuder/filter pack sampling system was used to measure the daily concentrations of water soluble inorganic compounds of fine ($D_{p}< 2.5;{mu}m$) and coarse ($D_{p}<10{mu}m$m) size fractions of aerosol and related gases at Gosan super site during ABC-EAREX 2005. The mean concentrations for $HNO_{3},;HNO_{2},;NH_{3}$, were 0.39, 0.08, and $0.29;{mu}g/m^3$. respectively. Average concentrations of sulfate, nitrate, and ammonium in $PM_{2.5}$ were 3.39, 1.06, and $1.04;{mu}g/m^3$, which occupied about $26\%$ of total $PM_{2.5}$ mass. In particular, more than half of these ionic species were found in size of less than $2.5;{mu}m$. Gas phase nitric acid concentrations have shown high correlation coefficient with $HNO_{2}$(R=0.80) and $O_{3}$(R=0.78), implying the active photochemical reactions from its precursors. Equivalent molar ratios between major ion components, $NH_{4};^{+}/nss;SO_4;^{2-},(0.83;for;PM_{2.5},;0.86;for;PM_{10})$, revealed that the existing forms of the secondary aerosols were probably $(NH_{4})_{2}SO_{4};and;(NH_{4})_{3}H;(SO_{4})_{2}$. Especially, $(NH_{4};^{+}+K^{+}+Ca^{2+}+Mg^{2+})/(NO_{3};^{-}+nss;SO_{4};^{2-}) (0.99;for;PM_{2.5},;1.05;for;PM_{10})$ indicated that some of them existed not only as $NH_{4}NO_{3}$ but also as $CaSO_{4};or;KNO_{3}$, which pointed out the probability of influences from the abundant soil components during Asian dust (AD) periods. These neutralized types of secondary aerosols showed that pollutants could be aged and transported from a distance.