IEEE 802.15.4 low-rate Wireless Personal Area Networks (WPAN) are expected to provide ubiquitous networking between small personal/home devices and sensors with low power consumption and low cost features. The technology employs special CSMA/CA (Carrier Sense Multiple Access/collision Avoidance) to save power consumption for small or portable WPAN-enabled devices. In this paper, we simulation the slotted CSMA/CA of IEEE 802.15.4 MAC and evaluate its performance limit in order to grasp the characteristics of Medium Access Control (MAC) of IEEE 802.15.4 WPAN.