When the water jets heated up to the saturation temperature at a high line pressure are sprayed into a reduced (atmospheric) pressure through an air-assisted nozzle, the jets experience sudden exposure into a reduced pressure, get superheated and produce steam bubbles while atomization processes of jets are taking place. This process is called flash atomization. In this study the flash atomization of superheated water jets assisted by air has been studied. Sprays with flash atomization have been photographed at various water and air flow rates and water superheats. It has been found that the spray angle with flash atomization increases with water superheat and water flow rate but decreases with air flow rate. The degree of change of spray angle has been analyzed and correlated as a function of superheat, air and water flow rates.