This paper proposes method for determining exterior orientation parameters (EOPs) from the RPC mathematical camera model of the satellite image. SPOT satellite stereo pair is pre-tested using the proposed method. As results that, geopositioning errors are similar with those of the original EOPs. Differences between EOPs determined from the RPC and original EOPs were small. IKONOS Geo-level stereo pair is tested by the proposed method. Results of this method are compared with those of the RPC block adjustment method which have been verified in reported studies. Consequently, the proposed method showed accuracy similar to the RPC block adjustment method. The digital elevation models (DEMs) of sample area acquired by the two method almost did not have a difference.