- $RuO_2{cdot}xH_2O$ 박막의 가스채색 현상을 이용한 수소검지 광센서
- ㆍ 저자명
- 정현식,조현철,김경문,Cheong. Hyeon-Sik,Jo. Hyun-Chol,Kim. Kyung-Moon
- ㆍ 간행물명
- 한국수소 및 신에너지학회 논문집
- ㆍ 권/호정보
- 2005년|16권 1호|pp.9-16 (8 pages)
- ㆍ 발행정보
- 한국수소및신에너지학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
We studied the electrochromic properties of hydrated amorphous ruthenium oxide ($RuO_2{cdot}xH_2O$) thin films using in-situ Raman spectroscopy during electrochemical charging/discharging cycles. We have found that the principal effect of hydrogen insertion into $RuO_2{cdot}xH_2O$ is reduction of $Ru^{4+};to;Ru^{3+}$, and not formation of new bonds involving hydrogen. We compared the changes in the Raman spectrum of a gasochromic $Pd/RuO_2{cdot}xH_2O$ film as it is exposed to hydrogen gas with that of electrochemical hydrogen insertion. We tested the changes in the optical transmission of the $Pd/RuO_2{cdot}xH_2O$ film when exposed to hydrogen gas.