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인과 염소 함유 변성폴리에스테르와 APT-Trimer에 의한 PU 난연도료의 제조 및 도막물성
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  • 인과 염소 함유 변성폴리에스테르와 APT-Trimer에 의한 PU 난연도료의 제조 및 도막물성
  • Preparation and Physical Properties of PU Flame-Retardant Coatings Using Modified Polyester Containing Phosphorus/Chlorine and APT-Trimer
저자명
박홍수,조혜진,심일우,함현식,김승진,성기천,Park. Hong-Soo,Jo. Hye-Jin,Shim. Il-Woo,Hahm. Hyun-Sik,Kim. Seung-Jin,Sung. Ki-Chun
간행물명
한국유화학회지
권/호정보
2005년|22권 3호|pp.270-280 (11 pages)
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한국유화학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

To maximize a synergy effect in flame-retardancy of flame-retardant coatings, phosphorus and chlorine were introduced in polymer chains. Two-components PU flame-retardant modified polyesters (ABTTC-10C, -20C, -30C) were prepared by curing, at room temperature, of isocyanate (allophanate-trimer) and prepared modified polyesters which contain phosphorus and chlorine. To examine the film properties of the prepared flame-retardant coatings, film specimens were prepared with the prepared coatings. The film properties of ABTTC, ABTTC-10C and ABTTC-20C, which contain 0, 10 and 20wt%, 2,4-dichlorobenzoic acid (2,4-DCBA), respectively, were proved to be good, whereas the film properties of ABTTC-30C, which contains 30wt% 2,4-DCBA, were proved to be a little bit poor. Two kinds of flame retardancy tests, $45^{circ}$Meckel burner method and LOI method, were performed. With the $45^{circ}$Meckel burner method, three flame-retardant coatings except ABTTC showed less than 3.4 cm of char length, and showed less than 2 seconds of afterflaming and afterglow. From this result, the prepared flame-retardant coatings were proved to have the 1st grade flame retardancy. With the LOI method, the LOI values of the coatings containing more than 10wt% 2,4-DCBA were higher than 30wt%, which means that the coatings possess good flame-retardancy. From these results, it was found that synergistic effect in flame-retardancy was taken place by the introduced phosphorus and chlorine.