This study is to make pH 9 reduction by adding NaOH to 1, 3, 5, 7, 9, 11% solution of thioglycollic acid, cysteine, cysteamin, to add it on helically winded natural hair and colored hair and leave them for 20, 40, 60 minutes, to add $NaBrO_3$ oxidant for 15 minutes and to compare and analyze the wave form. This study showed the results of permanent using thioglycollic acid, cysteine, cysteamin. In the permanent wave form according to the kind of reductant, concentration, and processing time, there were a little difference between thioglycollic acid and cysteine. But cysteamine not only showed apparent difference but also formed strong and elastic wave. The permanent wave is affected by the diagonosis of hair, the choice of permanent solution and the processing time. Therefore the scientific diagonosis of hair is to be considered first of all. By choosing the kind of solution, the concentration and the processing time according to the results of hair diagonosis and wave form, we can prevent the lengthening and damage of hair.