This study was executed to know the best matrix of photochemical ozone reduction in the metropolitan area. For this object, we used the OZIPR(Ozone Isopleth Plotting Package for Research) model for comparing the effectiveness of VOCs and NOx amount variation about the ozone creation. Among the various ozone reduction scenarios, 50% reduction of VOCs from organic solvent and road traffic respectively was the best matrix for ozone reduction. Although it needs more accurate assessment and confirmation of VOCs and NOx emission amount data, according to existing data, the control of VOCs is the best way for photochemical ozone reduction in Seoul.