Groundwater recharge is defined in an addition of water to groundwater reservoir. Recently, many people have been moving to the Edwards aquifer and urban and agricultural industry have been expending. Hydrologists and water planning managers concern about insufficient groundwater amounts and irrigation water price variability. In this paper, I focus on estimates of local recharge volumes and quantify preferential flow through GIS technique. Chloride Mass Balance (CMB) and hydrochemical components have been widely applied to recharge rate and evaluate flow paths. The CMB method is based on relationship between wet-dry chloride deposition data and Rainfall data. These data are manipulated using ArcGIS. Especially, hydrochemical concentration distribution is good index for groundwater residence times or flow paths such as $[Mg^{2+}]/[Ca^{2+}],[Cl]$ and log$([Ca^{2+}]+[Mg^{2+}])/[Na^+]$. Well information such as hydrological-hydrochemical data are imported into ArcGIS and manipulated by interpolation techniques. For each potentiometric surface and water quality, point data are converted to spatial data through each Kriging and Inverse Distance Weighted (IDW) techniques.