In this work, we developed an accurate and efficient radiative finite volume method applicable for the complex 2D planar and 3D geometries using an unstructured-grid finite volume method. The present numerical model has fully been validated by several benchmark cases including the radiative heat transfer in quadrilateral enclosure with isothermal medium, tetrahedral enclosure, a three-dimensional idealized furnace, as well as convection-coupled radiative heat transfer in a square enclosure. The numerical results for all cases are well agreed with the previous results. Special emphasis is given to the parallelization of the unstructured-grid radiative FVM using the domain decomposition approach. Numerical results indicate that the present parallel unstruc­tured-grid FVM has the good performance in terms of accuracy, geometric flexibility, and computational efficiency.