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Photodissociation Dynamics of Formic Acid at 206 nm
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  • Photodissociation Dynamics of Formic Acid at 206 nm
  • Photodissociation Dynamics of Formic Acid at 206 nm
저자명
Kang. Tae-Yeon,Kim. Hong-Lae
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2006년|27권 12호|pp.1997-2001 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The photodissociation dynamics of formic acid (HCOOH) at 206 nm have been investigated from rotationally resolved laser induced fluorescence spectra of OH ($^2Pi$) fragments produced exclusively in the ground state. From the spectra, the rotational energy of the fragments was measured to be $820;{pm};50;cm^{-1}$. The translational energy released in the products, which is 87% of the total available energy of the system, was also measured from analyses of the Doppler profiles. Joining these data with quantum chemical molecular orbital calculations, we have concluded that the dissociation should take place along the S1 surface with an exit channel barrier and also that the energy partitioning is determined at the exit channel.